A shock tube kinetic study of allyl + allyl and allyl + OH recombination reactions at high temperatures
نویسندگان
چکیده
منابع مشابه
Catalytic Stereospecific Allyl–Allyl Cross-Coupling of Internal Allyl Electrophiles with AllylB(pin)
Application of internal electrophiles in catalytic stereospecific allyl-allyl cross-coupling enable the rapid construction of multisubstituted 1,5-dienes, including those with all carbon quaternary centers. Compounds with minimal steric differentiation can be synthesized with high enantiomeric excess.
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We developed catalytic intermolecular C(sp(3))-C(sp(3)) cross-couplings between various allyl alcohols and allyl boronates, which proceeded smoothly in the presence of nickel(0) under mild conditions to form 1,5-dienes with excellent linear- and γ-selectivity; the use of boronates proved to be crucial in terms of reactivity.
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ژورنال
عنوان ژورنال: Proceedings of the Combustion Institute
سال: 2019
ISSN: 1540-7489
DOI: 10.1016/j.proci.2018.05.176